The problem with non linked TRV heads is they can't stop the boiler from cycling. In the heart of winter you don't really need a wall thermostat, the modern modulating boiler will measure the return water temperature and by so doing adjust the output to what is required.
However once the boiler output hits the minimum then the boiler starts to cycle off/on, and by again monitoring the return water temperature can adjust the times of the on/off to reduce the cycling, but can't actually turn the boiler off completely as it would not know when to turn it on again.
So we are told we should fit a wall thermostat in a room normally kept cool, with no outside doors, on the ground floor, with no alternative heating so it can turn boiler off when we get warmer weather.
However in my house and most other houses such a room does not exist, so we look for a compromise. There is no reason why we should not have a wall thermostat in every room all wired in parallel so if any one called for heat the boiler would run, we would also need TRV's in every room to limit the room temperature when another room has called for heat, however in real terms likely two wall thermostats would be enough, as long as placed in a room which tends to be cool.
So in most houses the hall is likely the coolest room, the problem is when front door is opened we want rapid rewarming, so back to the compromise.
If in heart of winter the temperatures set on the TRV are too low for the wall thermostat to be activated, but in autumn and spring when there is less heat loss it can activate the wall thermostat that is ideal. Idea is once the wall thermostat switches off, it stays off, so an old bi-metal thermostat with neutral disconnected is likely the best, that is if the hall is kept at the same temperature all the time.
However today we like to think we are not wasting money heating an empty home, so in my case both the wall thermostat and the TRV are programmable, the problem now lies in setting the temperatures so they work together. I have found by experiment the TRV needs to be a degree or two lower than the wall thermostat if it is not going to switch off wall thermostat too early. But this will vary home to home.
Hive had a great idea, as to if it works I don't know, read some poor reports, but the idea is the wall thermostat is set low, but signals from the TRV's send a demand for heat to the wall thermostat when required and the wall thermostat will then run boiler for ½ hour, so while any TRV is sending demand for heat, the wall thermostat stays switched on. How this works when you access Hive with phone I don't know, I would assume to access the TRV heads rather than the wall thermostat, but I don't have Hive so don't know.
With my Nest gen 3 as I leave the house it detects my phone is not at home and if also my wife's phone is not at home, and the occupancy detection has not detected anyone walking around, then it turns the temperature down, so boiler switches off, even though the Energenie TRV's also have geofencing there is no point setting it up, as if boiler not running they can't heat the rooms. When either of us gets closer to home, the Nest turns heating up again. Not perfect as in my case the hall radiator is too far away from the Nest thermostat, so on arriving home I need to turn Nest down a degree, and around an hour latter back up, or I will get a hysteresis.
As said not perfect, it is a compromise, yes I could have selected better, but it would have required new wires, and I am lazy and did not want to thread new cables from the flat where the boiler is, to the main house, and it works reasonably well.
I have got Nest Mini's and in theory I can tell the mini what I want, however they do make errors, I will say turn off music, and it replies turning off 5 switches and plunges me into darkness as it turns off the lights, so simply don't trust it with heating. So I can see with PC what is going on, or phone, but don't trust the Nest Mini so get some thing like this
today actually two light switches removed and a 4 output extension lead added, in theory could use IFTTT in summer to turn on AC unit, in practice I look at room temperature and switch on manually using Plug in switch/m as it shows there, so I can see the power it is using, so know if actually switched on.
I think impossible for reasonable money to get perfect system, so you have to decide what is near enough.