Yes, let one coat go tacky. First application is quite weak and primes the surface, second a bit stronger. If you're applying to a porous surface it won't seal the surface completely, it will simply reduce the porosity thus stopping the porous surface sucking all the water out of your plaster as soon as it touches the wall.
Even if the PVA does seal the wall completely, because the PVA itself has absorbed into the porous surface it will have created a strong bond to the surface so isn't likely to peel off, taking your skim coat with it.
I have skimmed a non porous surface before now, first using two coats of neat PVA and the skim did bond OK but it just slid about all over the place when I was laying it on and took ages to go off. It wasn't easy to finish but I got there in the end.
Regards
Fred