One radiator in the system should not have a TRV fitted. It's usually the one in the hallway which is the coldest part of your house. It's also the place you fit your programmer stat. The stat controls the heat demand by reading the room temp. If you had a TRV fitted they would constantly fight each other.
For example, if your radiator shuts off at 20 degrees and your stat is calling for heat to 21 degrees, your heating will run constantly because you will never reach 21 degrees as your radiator will not excees 20 degrees.
Not quite correct, a TRV has a range, depending on the head a mechanical head around 6ºC and an electronic head around 2ºC the wall thermostat also has a range between on and off, between 0.5ºC and 1ºC, so if radiator starts to close at 19ºC and the wall thermostat set to 20ºC then on a cold day the wall thermostat will never turn off and the radiator will vary in temperature to maintain the room temperature, and the boiler will modulate to match, keeping the rooms spot on temperature without any hysteresis, but on warmer days the room will get slightly warmer so then the wall thermostat will turn boiler off.
Well that is the theroy, in practice the wall thermostat is often poorly placed, it should be on the wall opposite to the radiator so the thermals cause a flow of air,
so there will naturally be a difference between the two thermostats, the TRV is at bottom of radiator so it samples the returning air, so will be cooler than the wall thermostat which is also often a lot higher up on the wall. Add to this often the wall thermostat is in the hall, and not placed so the thermals will naturally cause air to flow past it, even worse some times there is a stair case which means the hot air never reaches the wall thermostat it over heats upstairs first.
So at the moment my central heating is not running, it is timed to run at a lower temperature over night, so sitting at 18ºC
the radiator TRV is
sitting at 15ºC a whole 3ºC lower in the same room, as one lower down, and two nearer to the front door. This differential will vary home to home, and also summer and winter, in the summer with no central heating running the two show the same temperature. So it is a balancing act to get the two thermostats to work together rather than fighting each other, which one requires some temperature read out as shown to be able to set, having a TRV with *123456 is about as much good as a chocolate fire guard, however once set then the electronic head can be swapped back to a mechanical as the wall thermostat now set and lock shield now set so can set the TRV with trial and error, but to start with it needs the read out in ºC.
My house has three makes of electronic head, the cheap (£15 each in 2019) eQ-3 do not show current, only target, but the wifi connected ones
in both cases show the target and current temperature. However rather than carefully setting the TRV's and wall thermostat to work together by carefully setting the temperatures, it is far easier to get TRV heads which link to the wall thermostat/hub. This
has to be far easier than trying to match the TRV and wall thermostat by adjusting temperatures and lock shield valve settings. However it costs more. There are a few makes, Honeywell Evohome, Drayton Wiser, and Hive to name a few, but the silly one I have Nest Gen 3 does not with the UK version have any linked TRV heads, and I am a cheap skate and will not pay out for yet another wall thermostat.