Over time, alkaline batteries are prone to leaking potassium hydroxide, a caustic agent that can cause respiratory, eye and skin irritation. This can be avoided by not attempting to recharge alkaline cells, not mixing different battery types in the same device, replacing all of the batteries at the same time, storing in a dry place, and removing batteries for storage of devices.
According to type either a steel or zinc outer shell will likely fail with any type of recharging and with so many rechargeable batteries now available it would be silly to risk the damage to health and equipment by recharging primary cells.