Few things are impossible, but one sensible thing about the regs is that they recognise that it is not necessarily sensible to anticipate happenings are 'very unlikely'. Maybe you should marry bernardAnd when the unlikely event happens and the cable overheats and fails, does one say "Oh dear me I wonder why that happened" or even "I wonder why there are horrible smelly fumes in my kitchen?" ... Alternatively does one think ahead and say "For a few pounds more, that can't happen."
Furthermore, there are clearly some large safety margins built into the figures we work with, so I very much doubt that (even if the 'very unlikley' were to occur) 2.5mm² cable protected by a 32A MCB would ever come to any harm, let alone result in any "horrible smelly fumes". .... If the 'tabulated CCC" of Method C 2.5mm² cable were just 19% higher (i.e. about 32.13A), you presumably would be perfectly happy for it to be protected by a 32A OPD - do you really believe that (given the 'safety margins') that 19% make the difference between 'fine' and 'catastrophic'?
Kind Regards, John