The external controls / motorised valves are providing the required 'run' signal which results in the 'Boiler On' light being illuminated as your photo shows. Once this happens....
....the boiler should then continue to the next sequence of starting the fan, and when that is confirmed light the pilot, and then the burner. This isn't happening, so will require an RGI to investigate. As far as any external controls go they are asking the boiler for heat, and have switched the 'Boiler On' but the boiler is not responding, so there is definitely a boiler fault.
As has been said already, you have posted a photo of the room thermostat, but there would normally also be some form of time control where you can set the on/off times for the heating somewhere. Something similar to this:
Having said that and as per the above the external controls are definitely telling the boiler to 'go' but it isn't. So, I would suspect either the boiler PCB or possibly the air pressure switch that controls the fan.
....the boiler should then continue to the next sequence of starting the fan, and when that is confirmed light the pilot, and then the burner. This isn't happening, so will require an RGI to investigate. As far as any external controls go they are asking the boiler for heat, and have switched the 'Boiler On' but the boiler is not responding, so there is definitely a boiler fault.
As has been said already, you have posted a photo of the room thermostat, but there would normally also be some form of time control where you can set the on/off times for the heating somewhere. Something similar to this:
Having said that and as per the above the external controls are definitely telling the boiler to 'go' but it isn't. So, I would suspect either the boiler PCB or possibly the air pressure switch that controls the fan.