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@noseall has the answer in post #48. It's salt contamination, which once in the bricks/plaster, draws moisture from the room. The answer is to isolate the salts from the room. The easiest way is to strip it back to brick, and fix plasterboard using foam adhesive (that the salts can't cross - if you use wet dabs the salts get drawn through to the surface of the PB as the water in the dabs evaporates). Reskim and job jobbied.
These guys suggest a membrane to isolate https://www.tracebasementsystems.co.uk/post/damp-chimney-breasts, but I've found using foam adhesive works well in my house.
These guys suggest a membrane to isolate https://www.tracebasementsystems.co.uk/post/damp-chimney-breasts, but I've found using foam adhesive works well in my house.