How to improve thermal efficiency of one room?

otherwise you can't get an EPC cert. for the work when you come to sell

You can if you take photos of the insulation installation, or at least we did...the EPC inspector was quite happy to accept the photos.
 
the insulation I fitted internally on the extension was steico protect, but you will shrink the room a bit, it allows water vapour in and out, so helps to control humidity and improves the "decrement delay" more than PU foam does.
 
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