Thanks Stem, I've re-read your earlier note and studied the wiring in the main junction box, now understand better and happy with the thermostat bypass link. I've checked all my wiring, confirmed all connections tight and in line with requirements, also confirm I've connected the 'live' on Heat Link (L) to terminals (2) and (5) as well.
I've done a factory reset on the heatlink and re-booted the thermostat, gone through the setup process again. Now what is happening is that the heating is working but only when the hot water is timed or boosted to "on". I can live with this for a while if necessary, hoping to change boiler for a combi before too long, but it doesn't seem right. My suspicions are now with the 3-way valve - would you concur, and is it likely to be a wiring issue or mechanical sticking?
Your help really is much appreciated.