It's really hard to give you a step by step guide to sorting the issue.
Every installation is different and has its own quirks and nuances.
If all components have been tested for working order and replaced where necessary then it's all down to circulation performance and this could be hindered by airlocks, blockages and original installation design defects (or a combination thereof).
The usual method involves a combination of isolating various parts of the system (rads etc) and concentrating the power of the pump on the remaing circuit to open up pathways, getting air out and encouraging "clots" of detritus to break up into suspension. Chemicals can help with this.
Your are, in effect, trying to short circuit the system.
You can also try linking rad valves with a length of plastic pipe, to bypass them and give the secondary circuit less resistance to encourage flow, this also helps clear blockages in radiator feed pipes.
Also note that your circulation pump is not in an ideal orientation.
Yours is in the bottom right orientation above.
Your pump may also be tired and not giving the oomph needed to get things moving.