the boiler would be the same 35kw size.
Lost me there, Netaheat is 35Kw?
A few things to bear in mind......
Your system will easily be over 30 years old.
Hence, good chance wear and tear likely to show up weeps and leaks if system is pressurised.
Your boiler will either be 10/16 or 16/22 ie 10-16Kw or 16-22Kw
Heat input for these boilers is 20 and 28kW
There is a good chance your boiler is a 16/22 and your house unlikely to need 20Kw heat output
If plumbing is correct, am almost confident it will be as it will have been fitted by a time served professional, gas line will easily support 24Kw heat only boiler (or Intergas combi fitted as open vented with combi supplying kitchen/ utility hot water and cylinder the bathrooms).
Open vented will not stress your heating system
IG Combi (as open vented) will free up hot water cylinder of consistent hot water requirement in the kitchen
IG will still provide hot water if pump fails
Alternative-Ideal Logic Plus heat only open vented boiler
Get rid of the cold water storage cistern and fit unvented cylinder
Use good control system eg Honeywell Evohome for heat where it is needed.
I would be fitting Megnaclean to trap 30 year plus of system sediment in the system