Now this does involve delving into the wiring centre!So I am back to the original question on how to wire it please.
They don't want to make it easy for you
Taking the thermostat first, and assuming that you wish to mount the new stat where the old one is and reuse its wiring...
On the neoStat V2, connect:
Brown to L
Blue to N
Safely isolate the green/yellow earth wire in a separate terminal block (there doesn't appear to be an earth terminal on the neoStat)
Black to A2
And a link wire between L and A1
In the wiring centre, disconnect the wire from terminal 4 (probably, as we haven't seen inside your wiring centre yet!) going to the ST6400C (black wire?)
And replace it with a link wire between L (Terminal 1) and terminal 4.
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