I asked my plumber about my oil boiler, in my case a Bosch, and he said there was no run on built into the boiler to cool it after flame had extinguished so to put a motorised valve on the domestic hot water (DHW) would but extra strain on the boiler, the only option is either the old C plan or the Y plan as in both cases the default is DHW open so thermo syphon will allow the circulating water to cool.
The C plan had three stages, as time went on.
Stage 1 was really where the central heating was simply to have a warm bedroom to get up and go to bed in, it was traditionally on a timer and would fire up twice a day, morning and evening, and the open fire would be used during the day, they used a timer like this
so you had an option of once or twice a day, DHW only or DHW plus CH. The method of stopping the central heating working was to simply turn off the pump, but often the water would thermo syphon through upstairs radiators anyway, but they would not get to full heat, minimum time was around 2 hours a day, and we found that was a lot longer than required. I could result in either water not hot enough in summer, with legionnaires being a worry or getting up stairs radiators hot in the summer.
So for summer use only there was an addition, and a thermostat was fixed to the DHW tank, this means in suyou mmer it can be left on 24/7 and the boiler will only fire up when required. However in winter no control of DHW.
The next was to have the tank thermostat work a motorised valve, this means you can set the tank water temperature to under that of central heating circulating water, and you can actually have central heating without DHW, but it means no cooling for the boiler when switched off.
In my house we also have a flat under the house, so two pumps, and motorised valves so flat and house independent for central heating, but the DHW is always on when CH running either flat or house, but can be also run on a timed run without the central heating working, and the DHW is controlled with Nest Gen 3 similar to diagram shown, in summer the boiler is set to run ½ hour a day 5 days a week. That is enough to give us hot water, in real terms it does not run ½ hour as the return water gets too hot and boiler closes down after 20 minutes, I would prefer a thermostat on the water tank, but that is two floors above the boiler and getting three and earth cable between the two is not going to be easy.
Both Nest and Hive will both give DHW on it's own, but in a completely different way, Hive uses a software fix, Nest uses a hard wire fix, with Hive you do not have volt free contacts, so it has to use software, Nest does have volt free contacts, so instead of NO feeding the boiler as normal, the Com feeds the boiler, which is maybe why the installer said it can't be done.
You may need a motorised valve to stop the CH upstairs from thermo syphon, but in most houses simply turning off the pump is enough, only reason for motorised valves in my house, was if flat only ran it would push water around in reverse direction in house, and if house only ran water would be pushed round in reverse direction in the flat.
So I have only timed control for DHW, but so easy to select boost with Nest not really a problem, if going to have a bath I turn on boost other wise ½ hour except for 2 days is enough with the original ½ inch insulation on the tank. Do want to fit a jacket, but lock down stopped me getting one.