Contactor comes after MCB's, exactly as you have drawn your second diagram.
Thanks Harry. I figured that was the case, but you mentioned using a 3-phase contactor to control all of the heaters, so I wasn't sure if the circuit protection would be affected by having all radials on or off.
Apologies also to you and MeldrewsMate for taking so long to get back to you. Shortly after my last message I ordered a pair of 20A contactors from Screwfix, as well as a 6A MCB for the control circuit.
I also found this two-gang switch on Amazon for a reasonable price:
https://www.amazon.co.uk/gp/product/B07PGYKF4M/ref=ppx_yo_dt_b_asin_title_o04_s00?ie=UTF8&psc=1
I already had some spare cable and a pattress box so, for under £40, I have everything I need to control the storage heaters remotely. Of course, I won't be able to set the input/output dials on the heaters, but at least I can get them up and running the night before I stay at the flat, or switch them off when this weather improves!
).
I've prepared a breadboard prototype of the circuits and connected the switch to the Wifi (once I figured it out, it connected first time, and the app works well, even via Google Home).
The contactors make a reassuring thud when activated, and a bit of a buzz, but this shouldn't be a problem once fitted in the CU and the cupboard door closed.
The biggest challenge now will be the feeds between the two CUs, and back to the neutral busbar in the main CU. The knockouts in the bottom of each CU are virtually inaccessible, and space is tight.
Details.... details...
Thanks again for all your help.
NB