@polesapart, BlueLoo, Harry, Marty: Thank you Gentlemen!
Unfortunately other committments prevented me from tracing the source of the flexibe grey feed into the expansion tank. But many thanks PolesApart for your clearly explained & helpful post #37. I picked up the filling loop from Screwfix about 3 hours ago. I've ordered a bike pump with pressure gauge and Schrader valve coupler from Amazon, which is due for delivery tomorrow, for repressurising the air bladder of the expansion vessel, if this is required. I also ordered Jubilee clips from Toolstation to make my garden hose connection to the ground floor rad's escape valve watertight. This too is due in tomorrow.
Once all the bits'n'bobs are to hand, I will drain the system via the ground floor hall rad's escape valve, after bunging the two non-garage outlets in the loft water tank & shutting its ball valve, and opening the air-vents of the rads.
That done, I'll undo the compression nuts at either end of the flexible braided connector between the flexible grey feed to the EV and the EV itself, then remove this connector. I'll keep a tupperware container under the connector being loosened to catch any escaping water.
I'll then loosen the large diameter Jubilee clip holding up the EV, then rotate the EV to undo the water input feed at the top of the EV. My brother will be helping me out in the EV removal process. Once the EV is removed, I'll empty its water contents, and pressurise the air bladder to 1.5 bar with the bike pump.
Then back goes the EV into its Jubilee clip. Then the water inlet to the EV is screwed back on with some PTFE tape. The Jubilee clip is then tightened. Next, in goes the new loop connector from Screwfix, ensuring its in the right direction. As PolesApart recommends, I'll retain the olives from the previous loop connector, discard the olives from the new loop connector and tighten the compression fittings with some more PTFE tape (some on the threads of the connector males and some wrapped on the tube between the nut and the olive (to prevent weeping). ALL THIS ASSUMES THAT THE OLD OLIVES CAN SLIDE OFF their respective tubes, because if they are stuck in place then I will not be able to remove them in order to put in the compression nuts.
If the old olives are stuck in place and refuse to slide off even with WD40, then its Junior Hacksaw time, gingerly cutting into the olives without damaging the underlying tubing, ALWAYS A DELICATE OPERATION! Once the cut is deep enough, I'll use a flat screwdriver to wedge into the groove and twist to split the olive at that point. Please correct/advise me if I'm doing this wrong.
With the EV all connected up, it time to unbung the tank and fill up the system, see my post #9 for details of how I'll do this.
EDIT: I STRONGLY SUSPECT THAT THE EXISTING BRAIDED COUPLER IS THE FAULT. BECAUSE I ONCE TWISTED THE FLIMSY PLASTIC KNOBS ON THE VALVES THE WRONG WAY AND THE KNOBS SPLIT OPEN. I THEN HAD TO USE A PAIR OF GRIPS TO HOLD THE FLATS ON VALVE LUGS AND TWIST THE LUGS UNTIL THE FLATS WERE PARALLEL WITH THE BRAIDED LOOP. REALLY SHODDY CONSTRUCTION!
EDIT2 : THE PENNY DROPPED! I FINALLY UNDERSTOOD WHAT POLES WAS SAYING. IF I RETAINED THE OLD OLIVES
AND THE OLD COMPRESSION NUTS THEN THERE WOULD BE NO NEED TO REMOVE THE OLD OLIVES AND I CAN PROCEED AS IF THE OLD OLIVES & NUTS ARE THOSE OF THE NEW COUPLING. OBVIOUSLY I WILL NEED TO APPLY THE PTFE TAPE AS I DESCRIBED EARLIER IN THIS POST.