Okay conclusions - I believe the smell in the downstairs loo is now gone, but the main bathroom remains. It did seemingly go for a while but is now definitely back - why I have no idea, but at least (I think) I've solved one of the two problems. So today I have removed the temp white ducting from the main bathroom stack (and emptied the gathered condensation), and refitted the AAV that was there before, so back to square one. The other stack though I have now routed solid pipe work, using an adjustable angle connector onto the top of the stack, and then solid pipework up to the black solid flexi pipe off the roof tile. I have nicked a second black solid flexi pipe from another roof vent and back to backed it using an offcut of soil pile, as this was the most straight forward thing to do given the route, and without spending a fortune on various solid pipe connectors. Weight is supported by an array of interconnected cable ties off a rafter. Hopefully this is okay..