It is a Y plan, one set of valve wiring and its got a white wire in it as one of the 5 wires.
For 'Y Plan' with a single 3 port motorised valve, there should be a wire from the 'HW off' on your existing programmer that goes to the Grey wire on the motorised valve.
That will connect to the 'hot water satisfied' on the Heatlink
A wire from cylinder stat Sat terminal must also be connected to the grey wire/HW Sat, i.e. three wires connected together.